Beginners are best advised to learn basic concepts from a 2 x 2 x 2 Sudoku. You'll always find it easier to extend it to the regular 3 x 3 x 3 Sudoku.
You can subscribe to the free newseltter that teaches you from the basics using 2 x 2 x 2 Sudoku at
http://www.howtosolvesudokupuzzles.com .
Coming to the problem at hand, em's method is effective but somewhat cerebral; however, thankfully, we have a method that is less cerebral though it may consume slightly more time. With practice, you can learn to solve faster even with this method.
You resort to this simpler solution when you can go no farther. Just take one of the cells with multiple possible values, assume one value & try to resolve. If there is any row or column or major square of 3x3 where you have a conflict, then this assumption must be wrong. Make the other assumption, and try to solve.
For example, take Cell (1,4), i.e., r1c4. Try with the value '1' and it solves the puzzle. You've got the answer. Try with the other value '8' and you get a conflict. Sometimes, you may get answers in both cases, and then you know it has 2 (or more) possible answers.
Hope it helps.