People have different ideas about the meaning of the term guessing and a whole lot has been written about the rights and wrongs of it. I think that generally we say that puzzles that have more than one solution require guessing as there will be places with more than one option. For this reason guessing usually has a negative connotation.
To me guessing also implies that the person solving the puzzle is happy to accept any candidate because it works - without caring too much about understanding why or if its the only answer.
What you seem to be talking about is one form of trialling - testing a candidate in a logical series of steps to see if it works. Puzzles with one solution can be solved by a variety of trialling techniques, including randomly selecting this or that candidate and giving it a go. The chains that Crazy Girl mentions are a pretty obvious example of trialling in an advanced solving technique, but even a quick flash round the brain cells to determine the last clue in a row involves trialling in the sense that its checking the viability of this number in this place as against other numbers and other places.
A quick inference like this or recognising say, a hidden pair, certainly doesnt feel like trialling. All the examples of hidden pairs or whatever that weve done up till now, have imprinted the pattern into our brains so that we can choose the right candidate without going through all the working out. We recognise the pattern rather than the logic behind it. It has been said that were no longer trialling when its automatic. Perhaps we could call it intuiting - but the trialling process is an integral part of the pattern we recognised in the first place.
This has become a very long-winded reply, hope you havent nodded off.
Personally I dont like the technique youre talking about - trialling candidates until you reach a dead end, backtracking and starting again with another number. To me thats boring and tedious and if that was the only way to solve Sudoku I wouldnt do it.
What I find most satisfying is learning to understand and recognise the techniques and patterns that eliminate numbers without a lot of trialling. That to me is the challenging and rewarding part even more than finding the solution. However its a personal thing its a game after all, and we need to look for whatever makes it fun for us.